Preliminary Studies of Cassava Leaves’ Ability to Remove Dyes from Water

Chairunnisa Chairunnisa, Yuni Lisafitri

Abstract


Low-cost adsorbents from cassava leaves (CLP) were prepared by simply washing the leaf powder with deionized water. The adsorption of methylene blue (MB) from the aqueous solution was measured in order to examine the adsorbent performance. The effect of the pH of the solution was studied by varying pH from 2 to 10. The kinetics of MB adsorption onto CLP followed the pseudo-second-order kinetic model with a k-value of 0.087907 g mg-1 min-1 and 0.094081 g mg-1 min-1 for CLP before and after washing, respectively. The adsorption isotherm for both adsorbents followed the Langmuir isotherm model with qm values of 178.5 mg g-1 and 243.9 mg g-1. The existence of disturber ions was investigated by adding NaCl into the MB solutions at a variety of concentrations.

Keywords


adsorption; biosorbent; cassava leaves; methylene blue

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References


Shakoor, S. & Nasar, A., Journal of the Taiwan Institute of Chemical Engineers Removal of Methylene Blue Dye From Artificially Contaminated Water Using Citrus Limetta Peel Waste as a Very Low Cost Adsorbent, J. Taiwan Inst. Chem. Eng., 66, pp. 154-163, 2016.

Bhatnagar, A. & Sillanpää, M., Utilization of Agro-Industrial and Municipal Waste Materials as Potential Adsorbents for Water Treatment — A Review, Chemical Engineering Journal, 157(1-2), pp. 277-296, 2010.

Awoyinka, A. F., Abegunde, V.O. & Adewusi, S.R.A., Nutrient Content of Young Cassava Leaves and Assessment of Their Acceptance as a Green Vegetable in Nigeria, Plant Foods for Human Nutrition, 47, pp. 21-28, 1995.

Oresegun, A., Fagbenro, O.A., Ilona, P. & Edah, B., Nutritional and Anti-Nutritional Composition of Cassava Leaf Protein Concentrate from Six Cassava Varieties for Use in Aqua Feed, Cogent Food Agric., 62(1), pp. 1-6, 2016.

Louis, N.S.M. & Thomas, S., Activated Carbon from Tapioca Leaves for Treating Dye Waste Water, pp. 2-3, 2013.

Silva, T.L., Cazetta, A.L., Souza, P.S.C., Zhang, T., Asefa, T. & Almeida, V.C., Mesoporous Activated Carbon Fibers Synthesized from Denim Fabric Waste: Efficient Adsorbents for Removal of Textile Dye From Aqueous Solutions, J. Clean. Prod., 171, pp. 482-490, 2018.

Yan, J., Huang, Y., Miao, Y., Weei, W. & Liu, T., Polydopamine-Coated Electrospun Poly (Vinyl Alcohol)/Poly (Acrylic Acid) Membranes as Efficient Dye Adsorbent with Good Recyclability, J. Hazard. Mater, 283, pp. 730-739, 2015.

Dada, A.O, Olalekan, A.P., Olatunya, A.M & Dada, O., Langmuir, Freundlich, Temkin and Dubinin – Radushkevich Isotherms Studies of Equilibrium Sorption of Zn2+ Unto Phosphoric Acid Modified Rice Husk, IOSR Journal of Applied Chemistry, 3(1), pp. 38-45, 2012.

Abdelkarim, S., Mohammed, H. & Nouredine, B., iMedPub Journals Trends in Green Chemistry Sorption of Methylene Blue Dye from Aqueous Solution Using an Agricultural Waste Abstract, pp. 1-7, 2017.

Jawad, A.H., Razuan, R., Nelson, J. & Wilson, L.D., Adsorption and Mechanism Study for Methylene Blue Dye Removal with Carbonized Watermelon (Citrullus Lanatus) Rind Prepared via One-Step Liquid Phase H2SO4 Activation, Surfaces and Interfaces, 16, pp. 76-84, 2019.

Pereira, H., Carvalho, D., Huang, J., Zhao, M. & Liu, G., Improvement of Methylene Blue Removal by Electrocoagulation/Banana Peel Adsorption Coupling in A Batch System, Alexandria Eng. J., 54(3), pp. 777-786, 2015.

Nartey, F., Studies on Cassava, Manihot utilissima. II. Biosynthesis of Asparagine‐14C from 14C‐labelled Hydrogen Cyanide and its Relations with Cyanogenesis, Physiologia Plantarum, 22(5), pp. 1085-1096, 1969.

Burns, A.E., Gleadow, R.M., Zacarias, M., Miller, R.E. & Cavagnaro, T.R., Variations in the Chemical Composition of Cassava (Manihot esculenta Crantz) Leaves and Roots as Affected by Genotypic and Environmental Variation, J. Agric. Food. Chem., 60(19), pp. 4946-4956, 2012.

Chairunnisa, Siswanta, D., Suratman, A. & Tanaka, S., Shirasu Balloons and Polydopamine-Modified Shirasu Balloons for Adsorption of Methylene Blue, Water, Air, & Soil Pollution, 227, Article number 412, pp.1-11, 2016.

Wong, S., Adsorption of Anionic Dyes on Spent Tea Leaves Modi Fi Ed with Polyethyleneimine ( PEI-STL ), J. Clean. Prod., 206, pp. 394-406, 2019.

Majithiya, D., Yadav, A. & Tawde, S., Comparative Study of Azadirachta indica (Neem) Leaf Powder and Activated Charcoal as an Adsorbent for Removal of Chromium from an Aqueous Solution, Journal of Environmental Science and Sustainability, 1(1), pp. 21-27, 2013.

Afiqah, N., Mohamad, H., Biaw, L., Lim, L. & Usman, A., Environmental Technology & Innovation Enhancing Adsorption of Malachite Green Dye Using Base-Modified Artocarpus Odoratissimus Leaves as Adsorbents, Environ. Technol. Innov., 13, pp. 211-223, 2019.

Boudrahem, F. & Soualah, A., Adsorption of Lead (II) from Aqueous Solution by Using Leaves of Date Trees as an Adsorbent, Chem. Eng. Data, 56(5), pp. 1804-1812, 2011.

Pathak, P.D. & Mandavgane, S.A., Journal of Environmental Chemical Engineering Preparation and Characterization of Raw and Carbon From Banana Peel by Microwave Activation: Application in Citric Acid Adsorption, Biochem. Pharmacol., 3(4), pp. 2435-2447, 2015.

Lu, K., Journal of Colloid and Interface Science Adsorption Behavior and Mechanism of Fe-Mn Binary Oxide Nanoparticles : Adsorption of Methylene Blue, J. Colloid Interface Sci., 539, pp. 553-562, 2019.

Ponnusami, V., Gunasekar, V. & Srivastava, S.N., Kinetics of Methylene Blue Removal from Aqueous Solution Using Gulmohar (Delonix Regia) Plant Leaf Powder: Multivariate Regression Analysis, 169, pp. 119-127, 2009.

Yagub, M.T., Sen, T.K. & Ang, H.M., Equilibrium, Kinetics, and Thermodynamics of Methylene Blue Adsorption by Pine Tree Leaves, Water, Air and Soil Pollution, 223(8), pp. 5267-5282, 2012.

Setiabudi, H.D., Jusoh, R., Suhaimi, S.F.R.M. & Masrur, S.F., Adsorption of Methylene Blue onto Oil Palm (Elaeis Guineensis) Leaves: Process Optimization, Isotherm, Kinetics and Thermodynamic Studies, Journal of the Taiwan Institute of Chemical Engineers, 63, pp. 363-370, 2016.

Khodabandehloo, A., Rahbar-kelishami, A. & Shayesteh, H., Methylene Blue Removal Using Salix Babylonica (Weeping Willow) Leaves Powder as a Low-Cost Biosorbent In Batch Mode: Kinetic, Equilibrium, and Thermodynamic Studies, J. Mol. Liq., 244, pp. 540-548, 2017.

Peydayesh, M. & Rahbar-Kelishami, A., Adsorption of Methylene Blue onto Platanus Orientalis Leaf Powder: Kinetic, Equilibrium and Thermodynamic Studies, J. Ind. Eng. Chem., 21, pp. 1014-1019, 2015.




DOI: http://dx.doi.org/10.5614%2Fj.math.fund.sci.2020.52.1.5

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