Recovery of Lithium from Geothermal Fluid at Lumpur Sidoarjo by Adsorption Method

Lukman Noerochim, Gita Akbar Satriawangsa, Amien Widodo

Abstract


The recovery of lithium from geothermal fluid at Lumpur Sidoarjo, Indonesia was investigated employing an adsorption method with polymer membrane as container. The lithium concentration in geothermal fluid from Lumpur Sidoarjo used in the present study was about 5 mg/l. Lithium manganese oxide (LMO) was selected as a promising adsorbent material due to its non-toxic, topotactical behavior and low cost. In this study, LMO with single Li/Mn mole ratio was prepared, i.e. Li1.6Mn1.6O4. The adsorbent was synthesized by solid state reaction at 500 °C for 5 hrs. A lithium uptake yield from the geothermal fluid of around 6.6 mg/g was obtained.

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References


Jaskula, B.W., Lithium, U.S. Geological Survey Mineral Commodity Summaries, pp. 94-95, 2013.

David, R.J., Simon, S.A., Swarbrick, R.E. & Tingay, M.J., Probabilistic longevity estimate for the LUSI mud volcano, East Java, Journal of the Geological Society, 168, pp. 517-523, 2010.

Tanikawa, W., The Mechanism of Overpressure Generation in the LUSI Mud Volcano, E-Proceeding Symposium on Future Lusi, BPLS, Surabaya, Indonesia, 2011.

Ooi, K., Miyai, Y. & Katoh, S., Recovery of Lithium from Seawater by Manganese Oxide Adsorbent, Separation Science and Technology, 21(8), pp. 755-766, 1986.

Chitrakar, R., Kanoh, H., Miyai, Y. & Ooi, K., Recovery of Lithium from Seawater Using Manganese Oxide Adsorbent (H1.6Mn1.6O4) Derivied from Li1.6Mn1.6O, Ind. Eng. Chem. Res., 40, pp. 2054-2058, 2001.

Kitajou, A., Suzuki, T., Nishihama, S. & Yoshizuka, K. Selective Recovery of Lithium From Seawater Using A Novel MnO2 Adsorbent II-Enhancement of Lithium Ion Selectivity of The Adsorbent, Ars Separatoria Acta, 2, pp. 97-106, 2003.

Wang, L., Ma, W., Liu, R., Yan Li, H. & Gong Meng, C., Correlation between Li+ Adsorption Capacity and the Preparation Conditions of Spinel Lithium Manganese Precursor, Solid State Ionics, 177, pp. 1421-142, 2006.

Noerochim, L., Satriawangsa, G.A., Susanti, D. & Widodo, A., Synthesis and Characterization of Lithium Manganese Oxide with Different Ratio of Mole on Lithium Recovery Process from Geothermal Fluid of Lumpur Sidoarjo, Journal of Materials Science and Chemical Engineering, 3, pp. 56-62, 2015.

Wigayati, E.M., Febrianto, E.Y. & A. Fajar, Synthesize of LiMnO as Electrode for Solid Electrolyte Lithium Battery, Jurnal Sains Materi Indonesia., Special Edition, pp. 201-204, December 2008. (Text in Indonesian)

Lagashetty, Havanoor, V., Basavaraja S. & Venkataraman, A., Combustion Synthesis of LiMn2O4 by Thermal Decomposition of Oxalate Precursors, Indian J. Chem. Tech., 15, pp. 41-44, 2008.




DOI: http://dx.doi.org/10.5614%2Fj.eng.technol.sci.2016.48.2.6

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