Investigation of Alkaline Surface Treatment Effected on Flax Fibre Woven Fabric with Biodegradable Polymer Based on Mechanical Properties
DOI:
https://doi.org/10.5614/j.eng.technol.sci.2020.52.5.6Keywords:
Fibre surface treatment, natural fibre, biodegradable polymer, thin filmAbstract
Biodegradable polymers such as polylactic acid (PLA) are used nowadays due to their degradability, durability and environmentally friendly properties. Alkaline surface treatment of natural fibres is used to increase the flexural properties of composites. This research investigated the flexural properties of dry compressed PLA, wet mix PLA, untreated flax/PLA and treated flax/PLA composites. The flax fibre was first treated with NaOH. The wet mix PLA was prepared via solvent casting with chloroform and dried at room temperature overnight followed by post-drying in an oven. The flax/PLA composites were fabricated using a hot press for 6 minutes. The wet mix PLA showed higher flexural strength compared to the dry compressed PLA. The treated flax fibre composite showed higher flexural strength compared to the untreated flax fibre. The flexural strength and elongation at break of the treated flax fibre composite was increased by 4.79% and 27.76%, respectively, while the flexural modulus decreased by 0.79% compared with the untreated flax composite. The treated flax composite also showed an improvement in impact properties, increasing its impact strength by about 3% and 10% at energy levels of 10J, 15J, and 17.5J compared with the untreated flax fibre. Therefore, the investigation of the surface treatment of flax in a PLA matrix based on its mechanical properties revealed better properties compared to untreated flax/PLA composite.Downloads
References
El-Tayeb, N.S.M., A Study on the Potential of Sugarcane Fibres/Polyester Composite for Tribological Applications, Wear, 265(1-2), pp. 223-235, 2008.
Idiculam, M., Boudenne, A., Umadevi, L., Ibos, L., Candau, Y. & Thomas, S., Thermophysical Properties of Natural Fibre Reinforced Polyester Composites, Compos. Sci. Technol., 66(15), pp. 2719-2725, 2006.
Joshi, S.V., Drzal, L.T., Mohanty, A.K. & Arora, S., Are Natural Fibre Composites Environmentally Superior to Glass Fibre Reinforced Composites, Compos. Part A Appl. Sci. Manuf., 35(3) pp. 371-376, 2004.
Ahmed, K.S., Vijayarangan, S. & Naidu, A.C.B., Elastic Properties, Notched Strength and Fracture Criterion in Untreated Woven Jute-Glass Fabric Reinforced Polyester Hybrid Composites, Mater. Des., 28(8), pp. 2287-2294, 2007.
Murali, G. & Pannirselvam, N., Flexural Strengthening of Reinforced Concrete Beams Using Fibre Reinforced Polymer Laminate: A Review, J. Eng. Appl. Sci., 6(11), pp. 41-47, 2011.
Bos, H.L., The Potential of Flax Fibres as Reinforcement for Composite Materials, PhD thesis, Technische Universiteit Eindhoven, the Netherlands, 2004.
Angelov, I., Wiedmer, S., Evstatiev, M., Friedrich, K. & Mennig, G., Pultrusion of A Flax/Polypropylene Yarn, Compos. Part A Appl. Sci. Manuf., 38(5), pp. 1431-1438, 2007.
Pandey, J.K., Ahn, S.H., Lee, C.S., Mohanty, A.K. & Misra, M., Recent Advances in the Application of Natural Fibre-Based Composites, Macromol. Mater. Eng., 295(11), pp. 975-989, 2010.
Summerscales, J., Virk, A. & Hall, W., A Review of Bast Fibres and Their Composites: Part 3 - Modelling, Compos. Part A Appl. Sci. Manuf., 44(1), pp. 132-139, 2013.
Wu, C., Lai, W. & Wang, C., Effects of Surface Modification on the Mechanical Properties of Flax/-Polypropylene Composites, Materials (Basel), 9(5), pp. 1-11, 2016.
Yan, L., Chouw, N. & Jayaraman, K., Flax Fibre and Its Composites - A Review, Compos. Part B Eng., 56, pp. 296-317, 2014.
Pickering, K.L., Efendy, M.G.A. & Le, T.M., A Review of Recent Developments in Natural Fibre Composites and Their Mechanical Performance, Compos. Part A Appl. Sci. Manuf., 83, pp. 98-112, 2016.
Morrison, W.H., Archibald, D.D., Sharma, H.S.S. & Akin, D.E., Chemical and Physical Characterization of Water- And Dew-Retted Flax Fibres," Ind. Crops Prod., 12(1), pp. 39-46, 2000.
Zhu, J., Zhu, H., Immonen, K., Brighton, J. & Abhyankar, H., Improving Mechanical Properties of Novel Flax/Tannin Composites through Different Chemical Treatments, Ind. Crops Prod., 67, pp. 346-354, 2015.
Xie, Y., Hill, C.A.S., Xiao, Z., Militz, H. & Mai, C., Silane Coupling Agents Used for Natural Fibre/Polymer Composites: A Review, Compos. Part A Appl. Sci. Manuf., 41(7), pp. 806-819, 2010.
Alix, S., Pectinase Treatments on Technical Fibres of Flax: Effects on Water Sorption and Mechanical Properties, Carbohydr. Polym., 87(1), pp. 177-185, 2012.
Huner, U., Effect of Chemical Surface Treatment on Flax-Reinforced Epoxy Composite, J. Nat. Fibres, 15(6), pp. 1-14, 2017.
Van de Weyenberg, I., Chi Truong, T., Vangrimde, B. & Verpoest, I., Improving the Properties of UD Flax Fibre Reinforced Composites by Applying an Alkaline Fibre Treatment, Compos. Part A Appl. Sci. Manuf., 37(9), pp. 1368-1376, 2006.
Thomas, L.G., Pistachio Shell Flakes and Flax Fibres as Reinforcements in Polyester Based, International Conference on Engineering and Information Technology, Kuala Lampur, Malaysia, pp. 17-24, 2017.
Drumright, R.E., Gruber, P.R. & Henton, D.E., Polylactic Acid Technology, Adv. Mater., 12(23), pp. 1841-1846, 2000.
Mohan, C., Manufacture and Mechanical Testing of Thin Film Composites Composed of Poly-lactic Acid and Nanocrystalline Cellulose, Degree project, The Faculty of the Materials Engineering Department, California Polytechnic State University, San Luis Obispo, 2014.
Fiore, V., Scalici, T., Calabrese, L., Valenza, A. & Proverbio, E., Effect of External Basalt Layers on Durability Behaviour of Flax Reinforced Composites, Compos. Part B Eng., 84, pp. 258-265, 2016.
Liu, W., Dong, Y., Liu, D., Bai, Y. & Lu, X., Polylactic Acid (PLA)/Cellulose Nanowhiskers (CNWs) Composite Nanofibres: Microstructural and Properties Analysis, J. Compos. Sci., 2(1), pp. 1-14, 2018.
Yan, L., Chouw, N. & Yuan, X., Improving the Mechanical Properties of Natural Fibre Fabric Reinforced Epoxy Composites by Alkali Treatment, J. Reinf. Plast. Compos., 31(6), pp. 425-437, 2012.
Shibata, S., Cao, Y. & Fukumoto, I., Press Forming of Short Natural Fibre-Reinforced Biodegradable Resin: Effects of Fibre Volume and Length on Flexural Properties, Polym. Test., 24(8), pp. 1005-1011, 2005.
Reddy, N. & Yang, Y., Biofibres from Agricultural Byproducts for Industrial Applications, Trends Biotechnol., 23(1), pp. 22-27, 2005.