Effect of Polystyrene Latex Addition on Size and Pore Volume of Porous Calcium Oxide Particles Prepared by Spray-Pyrolysis Method and Its Ability for SO2 Retention

Ricky Dwi Septianto; Ferry Iskandar; Mikrajuddin Abdullah; Khairurrijal Khairurrijal; Lee Myong Hwa

doi:10.5614/j.eng.technol.sci.2018.50.2.6

Authors

Ricky Dwi Septianto Physics of Electronic Materials Division, Department of Physics Faculty of Mathematics and Natural Sciences, Insitut Teknologi Bandung Jalan Ganesha 10, Bandung 40132
Ferry Iskandar Physics of Electronic Materials Division, Department of Physics Faculty of Mathematics and Natural Sciences, Insitut Teknologi Bandung Jalan Ganesha 10, Bandung 40132
Mikrajuddin Abdullah Physics of Electronic Materials Division, Department of Physics Faculty of Mathematics and Natural Sciences, Insitut Teknologi Bandung Jalan Ganesha 10, Bandung 40132
Khairurrijal Khairurrijal Physics of Electronic Materials Division, Department of Physics Faculty of Mathematics and Natural Sciences, Insitut Teknologi Bandung Jalan Ganesha 10, Bandung 40132
Lee Myong Hwa Thermochemical Energy System R&D Group, Korea Institute of Industrial Technology (KITECH), 89 Yangdaegiro-gil, Ipjang-myeon, Cheonan, Chungnam 31056,

DOI:

https://doi.org/10.5614/j.eng.technol.sci.2018.50.2.6

Keywords:

CaO, porous, polystyrene, spray-pyrolysis, SO2

Abstract

In this study, the effects of polystyrene (PS) latex addition on the particle morphology and the pore content of calcium oxide (CaO) were investigated. The CaO particles were prepared using an ultrasonic nebulizer-assisted spray-pyrolysis method with variation of the PS/Ca(NO₃)₂4H₂O mass ratio in the precursor. Good crystallinity of CaO was obtained at 825C of synthesis temperature under 2 l/min of nitrogen gas flow, which was confirmed by Fourier transform infrared (FTIR) spectroscopy and X-ray diffraction (XRD). According to scanning electron microscope (SEM) characterization, the CaO particles synthesized with 0 and 25 wt% PS addition had an almost spherical shape with an average size of 1.58 and 1.48 m, respectively. In addition, macropores were formed in the CaO particles prepared with 25 wt% PS addition that had an average pore diameter of 583.26 nm. Meanwhile, the CaO particles prepared with 75 wt% PS addition had a random shape and an average size of 1.41 m. The mesopore content was investigated by Barret-Joyner-Halenda (BJH) analysis, which showed improvement of the pore size from 3.45 nm to 5.42 nm for 0 and 25 wt% PS addition, respectively, which is proportional to the pore volume, pore surface area, and the capacity of SO₂ retention.

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Author Biography

Ferry Iskandar, Physics of Electronic Materials Division, Department of Physics Faculty of Mathematics and Natural Sciences, Insitut Teknologi Bandung Jalan Ganesha 10, Bandung 40132

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