Synthesis, Structure, Magnetic and Antibacterial Properties of polymeric [M(Quin)2(N(CN)2)2]? (M = Mn(II), Co(II); Quin = quinoline)
DOI:
https://doi.org/10.5614/j.math.fund.sci.2022.54.2.4Keywords:
Manganese(II) complex, Cobalt(II) complex, quinoline ligand, antiferromagnetic, antibacterialAbstract
Two complexes of [Mn(Quin)2(N(CN)2)2]? (1) and [Co(Quin)2(N(CN)2)2]? (2) were synthesized and characterized. The as-synthesized complexes crystallized in a triclinic lattice with a space group of P-1. The unit cell parameter of 1 was a = 7.5207(14) b = 7.7729(16) c = 9.5968(15) ? = 96.388(6) o, ? = 112.617(5) o, ? = 102.751(6) o, while for complex 2 it was a = 7.3942(10) b = 7.7960(10) c = 9.4907(13) ? = 96.631(4) o, ? = 112.742(4) o, ? = 102.458(4) o. The magnetic properties and antimicrobial properties of both polymeric complexes were examined by magnetic susceptibility and diffusion techniques, respectively. Complexes 1 and 2 both showed antiferromagnetic properties and had a higher inhibitory effect on the growth of Staphylococcus aureus than Salmonella typhi.
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