Rapid Synthesis of Graphene Oxide Derived from Biomass with Atmospheric Plasma Technology
DOI:
https://doi.org/10.5614/j.math.fund.sci.2024.56.1.5Keywords:
atmospheric plasma, graphene oxide, graphitization, plant biomass, synthesisAbstract
In this study, we explored a low-cost, green, and renewable approach utilizing biomass resources, i.e., coconut fronds, palm fronds, and rambutan stems, to rapidly synthesize graphene oxide via atmospheric plasma techniques. The plasma treatment, with argon gas as the plasma source and a power source of 960 W, lasted for 5 minutes. Graphene oxide (GO) was confirmed using SEM and TEM images with a C:O content ratio greater than 80% for all samples and the formation of graphene layers. The presence of a D-band and a G-band in Raman spectroscopy as well as O-H and C-O groups in the FTIR confirmed the existence of GO.
References
Radadiya, T.M., A Properties of Graphene, European Journal of Material Sciences, 2(1), pp. 6-18, 2015.
Fortugno, P., Musikhin, S., Shi, X., Wang, H., Wiggers H. & Schulz, C., Synthesis of Freestanding Few-layer Graphene in Microwave Plasma: The Role of Oxygen, Carbon N.Y., pp. 186, 560-573, 2022.
Chang, Y.C., Yen, C.C., Tsai, H.C., Chen, T.C., Yang, C.M., Chen, C.H. &. Woon, W.Y., Characteristics of Graphene Grown Through Low Power Capacitive Coupled Radio Frequency Plasma Enhanced Chemical Vapor Deposition, Carbon N.Y., 159, pp. 570-578, 2020.
Walimbe, P. & Chaudhari, M., State-of-the-art Advancements in Studies and Applications of Graphene: A Comprehensive Review, Materials Today Sustainability, 6, 100026, 2019.
Surekha, G., Krishnaiah, K.V., Ravi, N. & Padma Suvarna, R., FTIR, Raman And XRD Analysis of Graphene Oxide Films Prepared by Modified Hummers Method, in: J Phys Conf Ser, Institute of Physics Publishing, 1495(1), 012012, 2020.
Rudrapati, R., Graphene: Fabrication Methods, Properties, and Applications in Modern Industries, in Graphene Production and Application, IntechOpen, 1, 1-14, 2020.
Luong, D.X., Bets, K.V., Algozeeb, W.A., Stanford, M.G., Kittrell, C., Chen, W., Salvatierra, R.V., Ren, M., McHugh, E.A., Advincula, P.A., Wang, Z., Bhatt, M., Guo, H., Mancevski, V., Shahsavari, R., Yakobson, B.I. &. Tour, J.M., Gram-scale Bottom-up Flash Graphene Synthesis, Nature, 577(7792), pp. 647-651, 2020.
Safian, M.T.U., Umar, K. & Ibrahim, M.N.M., Synthesis and Scalability of Graphene and Its Derivatives: A Journey Towards Sustainable and Commercial Material, J Clean Prod., 318, 2021.
Chua, C.K. & Pumera, M., Chemical Reduction of Graphene Oxide: A Synthetic Chemistry Viewpoint, Chem Soc Rev., 43(1), pp. 291-312, 2014.
Dreyer, D.R., Park, S., Bielawski, C.W. & Ruoff, R.S., The Chemistry of Graphene Oxide, Chem Soc Rev., 39(1), pp. 228-240, 2010.
Naumov, A.V., Graphene Oxide: Fundamentals and Applications, 2017.
Eda, G. & Chhowalla, M., Chemically Derived Graphene Oxide: Towards Large-area Thin-film Electronics and Optoelectronics, Advanced Materials, 22(22), pp. 2392-2415, 2010.
Shah, J., Lopez-Mercado, J., Carreon, M.G., Lopez-Miranda, A. & Carreon, M.L., Plasma Synthesis of Graphene from Mango Peel, ACS Omega, 3(1), pp. 455-463, 2018.
Supriyanto, G., Rukman, N.K., Khoiron Nisa, A., Jannatin, M., Piere, B., Zakki Fahmi, M. & Septya Kusuma, H., Graphene Oxide from Indonesian Biomass: Synthesis and Characterization, BioResources, 13(3), pp. 4832-4840, 2018.
Ramli, R. & Hidayat, R., Graphene Oxide Based on Biomass Waste: Synthesis and Applications, in Graphene - A Wonder Material for Scientists and Engineers, IntechOpen, pp. 1-20, 2023.
Abbas, A., Eng, X.E., Ee, N., Saleem, F., Wu, D., Chen, W., Handayani, M., Tabish, T.A., Wai, N. & Lim, T.M., Development of Reduced Graphene Oxide from Biowaste as an Electrode Material for Vanadium Redox Flow Battery, J Energy Storage, 41, 102848, 2021.
Challa, A.A., Saha, N., Ngwabebhoh, F.A., Nguyen, H.T., Urbanek, P., Fei, H. & Saha, P., Synthesis and Characterization of Graphene Oxide from Residual Biomass, in: 2022 IEEE 12th International Conference Nanomaterials: Applications & Properties (NAP), IEEE, pp. 1-4, 2022.
Purawiardi, R.I., Dimyati, A., Handayani, A.H., Kismanto, A., Sari, Y.W., Maddu, A. & Elbersen, H.W., Plasma-assisted Pyrolysis for Converting Oil Palm Fronds into Reduced Graphite Oxide, in: IOP Conf Ser Earth Environ Sci, Institute of Physics, 1309(1), 2024.
Hanifa, I.I., Sunu, W. & Dwandaru, B., Synthesis and Characterization of Graphene Oxide based on Processed Graphite using Audiosonication Method, 8(1), 2021.
Gutirez-Cruz, A., Ruiz-Herndez, A.R., Vega-Clemente, J.F. & Luna-Gazc, D.G. & Campos-Delgado, J., A Review of Top-down and Bottom-up Synthesis Methods for the Production of Graphene, Graphene Oxide and Reduced Graphene Oxide, J. Mater Sci., 57(31), pp. 14543-14578, 2022.
Yu, H., Zhang, B., Bulin, C., Li, R. & Xing, R., High-efficient Synthesis of Graphene Oxide Based on Improved Hummers Method, Sci Rep, 6(1), pp. 1-7, 2016.
Ciptasari, N., Darsono, N., Handayani, M. & Soedarsono, J., Synthesis of Graphite Oxide using Hummers Method: Oxidation Time Influence, in: AIP Conf. Proc. 2382(1), 020010, 2021.
Thangaraj, B., Mumtaz, F., Abbas, Y., Anjum, D.H., Solomon, P.R. & Hassan, J., Synthesis of Graphene Oxide from Sugarcane Dry Leaves by Two-stage Pyrolysis, Molecules, 28(8), 3329, 2023.
Purawiardi, I., Kismanto, A., Hijrah Handayani, A., Maddu, A., Elbersen, W., Kartono, A., Widya Sari, Y. & Dimyati, A., Numerical Analysis for Predicting the Rate of Graphitization on Wood Biomass during the Plasma-assisted Pyrolysis, in: IOP Conf Ser Earth Environ Sci, Institute of Physics, 1354(1), 012017, 2024.
Wyss, K.M., Luong, D.X. & Tour, J.M., Large-scale Syntheses of 2D Materials: Flash Joule Heating and Other Methods, Advanced Materials, 34(8), 2106970, 2022.
Farid, M.A.A. & Andou, Y., A Route Towards Graphene from Lignocellulosic Biomass, J Clean Prod., 380, 135090, 2022.
Hidayah, N.M.S., Liu, W.W., Lai, C.W., Noriman, N.Z., Khe, C.S., Hashim, U. & Lee, H.C., Comparison on Graphite, Graphene Oxide and Reduced Graphene Oxide: Synthesis and Characterization, In: AIP Conf Proc, American Institute of Physics Inc., 1892(1), 2017.
Purawiardi, I., Analisis XRD untuk Logam Padat (XRD Analysis for Solid Metals), IPB Press, 2020.
Suryanarayana, C. & Norton, M.G., X-Ray Diffraction, Springer US, Boston, MA, 1998.
Darminto, D., Baqiya, M. & Asih, R., Pengembangan Bahan Karbon Dari Biomassa (Development of Carbon-based Materials from Biomass), ITS Press Surabaya, 2018.
Ji?kov A., Jankovsk O., Sofer, Z. & Sedmidubsk D., Synthesis and Applications of Graphene Oxide, Materials, 15(3), 920, 2022.
Smith, E. & Dent, G., Modern Raman Spectroscopy-a Practical Approach. John Wiley and Sons Ltd., Chichester, 2005.
Scardaci, V. & Compagnini, G., Raman Spectroscopy Investigation of Graphene Oxide Reduction by Laser Scribing, C (Basel), 7(2), 48, 2021.
Widyaningrum, B.A., Apriani, D. & Amanda, P., Synthesis and Characterization: Composite of Graphene Oxide Based Palm Kernel Shell Waste with Fe3O4, 22(2), 488372, 2021.
Kim, S.G., Park, O.K., Lee, J.H. & Ku, B.C., Layer-by-layer Assembled Graphene Oxide Films and Barrier Properties of Thermally Reduced Graphene Oxide Membranes, Carbon Letters, 14(4), pp. 247-250, 2013.
Emiru, T.F. & Ayele, D.W., Controlled Synthesis, Characterization and Reduction of Graphene Oxide: A Convenient Method for Large Scale Production, Egyptian Journal of Basic and Applied Sciences, 4(1), pp. 74-79, 2017.
Tiginyanu, I., Ursaki, V. & Popa, V., Ultra-thin Membranes for Sensor Applications, In: Nanocoatings and Ultra-thin Films, pp. 330-354, 2011.
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