The System of Gelled Foam of Clay-in-water Suspension for the Preparation of Lightweight Insulating Refractory: Part I. Formation and Gelling of Clay-Based Foam
Abstract
Under neutral conditions colloidal plates of clay in water are negatively charged. When the pH of the clay-in-water dispersion is lowered slightly, positive charges can develop on the edges of the clay plates giving rise to an edge-to-face type gelation. Sodium fluosilicate, which has a rather high acidity and which is very slightly soluble in water, can be used as gelling agent. By beating a clay slip containing, a surfaceactive agent "Teepool" and sodium fluosilicate, one can obtain a stable foam followed by formation of a firm gel. When then the wet gel is dried a solid foam product is built up.References
Murray, P., Livey, D.T., and William, J. in W.D. Kingery's Ceramic Fabrication Processes, 159, The Technologi Press of Massachusetts Institute of Technology and John Wiley & Sons, Inc., New York; Chapmen & Hall, Limited. London (1958).
Norton, F.H., Refractories, 142, 3rd. ed., McGraw-Hill Book Company, Inc., New York; Toronto: London (1949).
Ibid: Ref. 2, 143.
Chem. Abstr. 25, 5747 (1931).
Ibid. Ref. 2, 144.
Ibid. Ref. 2, 144
Chem. Abstr. 45, 6818c (1951).
Ibid. Ref. 2, 144
Van Alphen, J. Rubber Chemicals, 111 , Elsevier Publishing Company Amsterdam; London; New York; Princeton (1956).
Weiser, H.B., A Text book of Colloid Chemistry, 6, 2nd ed. John Wiley & Sons. Ins., New York; Chapman & Hall, Limited, London (1956).
Hauser, E.A., and Lynn, J.E., Experiments in Colloid Chemistry, 45, McGraw-Hill Book Company, Inc., New York; London (1940).
De Boer, J., in R. Kronig's Leerboek der Natuurkunde, 662, 3de verbeterde druk, Scheltema & Holkema's Bockhandel en Uitgeversmaatschappij. N.V., Amsterdam (1951).
Ibid. Ref. 10., 17-19.
Mc. Bain, J.W., Colloid Science 57, D.C. Heat and Company, Boston (1950)
Ibid. Ref. 10,355.
Hofman, U., in A. Kuhn's Kolloid Chemisches Taschenbuch, 198,4 teerweiterte Auflage, Akademische Verlagsgesellschaft, Geest & Portig, K.G. (1953).
Lewis, W.K., Squires, L., and Broughton, G., Industrial Chemistry of Colloidal and Amorphous Materials, 450, The Macmillen Company New York (1952).
Ibid. Ref. 14, 383.
Bridley G.W., in W.D. Kingery's Ceramic Fabrication Processes (see Ref. 1), 12.
Ibid. Ref. 14, 378.
Ibid. Ref. 17, 187
Ibid. Ref. 14, 396
Ibid. Ref. 19, 17-18.
lbid. Ref. 19, 18
Ibid. Ref. 19, 18
Ibid. Ref. 16, 303
lbid. Ref. 17, 248
Hermans, P.H., in H.R. Kruyt's Colloid Science, Volt. II, 490, Else Publishing Company, Inc., New, York; Amsterdam; London; Brussels (1949).
Ibid. Ref. 28, 484.
Ibid. Ref. 17, 225.
Hampel, C.A, Chem. Eng. News. 27, Part II, 2421 (1949).
Chem. Abstr. 20, 311 (1926).
Barron, H., Modern Rubber Chemistry, 255, D, van Nostrand Company, Ins., New York (1948); Chem. Abstr. 25, 473 (1931).
Perry, J.H. Chemical Engineerings' Handbook, 963, 3rd. ed., McGraw-Hill Publishing Company Ltd., New York; London; Toronto (1953).


