Enhanced Ionic Conductivity of Layered-MnO2 accompanied Morphology Evolution for Aqueous Zinc-Ion Battery
DOI:
https://doi.org/10.5614/MESIN.2024.30.1.4Abstract
Enhancing ionic conductivity is crucial for improving the performance of cathode materials in zinc-ion battery applications. In this study, nanoscale manipulation with nickel intercalation into the layered-MnO2 cathode structure was achieved through a hydrothermal reaction at 160C for 10 hours. The results of Ni-layered-MnO2 synthesis showed a distinctive peak of layered-MnO2 cathode, as indicated by XRD results, and increased conductivity; its ionic conductivity was analyzed through electrochemical impedance spectroscopy (EIS), enabling rapid diffusion of Zn2+ ions and electron transfer. The distinctive morphology and structure of Ni-doped layered-MnO2 through scanning electron microscope (SEM) contribute to enhanced ionic conductivity and facilitate ion transportation, positioning it as a promising cathode material for aqueous zinc-ion battery applications.
References
Xu, Y., et al., Recent Advances on Challenges and Strategies of Manganese Dioxide Cathodes for Aqueous Zinc-Ion Batteries, Energy & Environmental Materials, 6(6), p. e12575, 2023.
Huang, Y., et al., Flexible High Energy Density Zinc-Ion Batteries Enabled by Binder-Free Mno2/Reduced Graphene Oxide Electrode, npj Flexible Electronics, 2(1), 2018.
Gunaydin, S., et al., The Effect of CrFe2O4 Addition on the Ionic Conductivity Properties of Manganese-Substituted LiFeO2 Material, Journal of Electronic Materials, 53(1), pp 367-379, 2023.
Tu, T., Chen, L., & Li, L., The Function of Phenylphosphonic Acid on Diversifying the Property of Manganese Dioxide Applied in the Aqueous Zinc-Ion Battery, Electrochimica Acta, 2024.
Zhang, X., Yu, P., Zhang, H., Zhang, D., Sun, X., & Ma, Y., Rapid Hydrothermal Synthesis of Hierarchical Nanostructures Assembled from Ultrathin Birnessite-Type MnO2 Nanosheets for Supercapacitor Applications, Electrochimica Acta, 89, pp 523-529, 2013.
Xiao, W., Wang, D., & Lou, X.W., Shape-Controlled Synthesis of MnO2 Nanostructures with Enhanced Electrocatalytic Activity for Oxygen Reduction, The Journal of Physical Chemistry C, 114(3), pp 1694-1700, 2010.
Zhang, R., et al., Manipulating Intercalation-Extraction Mechanisms in Structurally Modulated ?-MnO2 Nanowires for High-Performance Aqueous Zinc-Ion Batteries, Chemical Engineering Journal, 433, 2022.
Zhu, S., Huo, W., Liu, X., & Zhang, Y., Birnessite Based Nanostructures for Supercapacitors: Challenges, Strategies and Prospects, Nanoscale Adv, 2(1), pp. 37-54, 2020.
Worku, A.K., Ayele, D.W., & Habtu, N.G., Influence of Nickel Doping on MnO2 nanoflowers as Electrocatalyst for Oxygen Reduction Reaction, SN Applied Sciences, 3(9), 2021.
Cai, N., Wang, K., Li, N., Huang, S., & Xiao, Q., Novel Sandwich Structured Chrysotile Fiber Separator for Advanced Lithium-Ion Batteries, Applied Clay Science, 183, 2019.
Patil, T.S., et al., Effect of Nickel (Ni) Ion Doping on the Morphology and Supercapacitive Performance of Mn3O4 Thin Films, Journal of Electronic Materials, 2023.
Wu, B., et al., Graphene Scroll-Coated alpha-MnO2 Nanowires as High-Performance Cathode Materials for Aqueous Zn-Ion Battery, Small, 14(13), p. e1703850, 2018.
Fang, G., et al., Suppressing Manganese Dissolution in Potassium Manganate with Rich Oxygen Defects Engaged High?Energy?Density and Durable Aqueous Zinc?Ion Battery, Advanced Functional Materials, 29(15), 2019.
Lee, B., et al., Critical Role of pH Evolution of Electrolyte in the Reaction Mechanism for Rechargeable Zinc Batteries, ChemSusChem, 9(20), pp. 2948-2956, 2016.
Zhang, T., et al., Fundamentals and Perspectives in Developing Zinc-Ion Battery Electrolytes: a Comprehensive Review, Energy & Environmental Science, 13 (12), pp. 4625-4665, 2020.