Particle Size Distribution and Rheolog ical Characteristic of Trimethylolethane Treated by Cationic Surfactant

Penulis

  • Yuli Setyo Indartono
  • Hiromoto Usui
  • Hiroshi Suzuki
  • Satoshi Tanaka
  • Kousuke Nakayama
  • Yoshiyuki Komoda
  • Tetsu Itotagawa

Abstrak

Trimethylolethane (TME) trihydrate particle suspended in water is a proper substance for latent heat transportation in cooling systems, since it has high heat transfer and thermal capacity. Additives, oleyl bishydroxyethyl methyl ammonium chloride as surfactant and sodium salicylate as counter-ion, were added into TME slurry to reduce its friction factor. Aditives influence on particle size distribution and rheological characteristic of TME are investigated in this study. It is found that the additives do not influence particle size at crystallization point, but they clearly inhibit further particle growth. By increasing molar ratio of counter-ion to surfactant, the particles do not grow at all. Increasing TME concentration reduces the apparent viscosity of TME with surfactant and increases critical shear rate for Shear Induced Structure (SIS) occurrence. By connecting this SIS phenomenon with previous data, it is found that there is a relation between the SIS and drag reduction for this drag-reducing TME suspension system.

Referensi

H. Kakiuchi, M. Yabe and M. Yamazaki, A Study

of Trimethylolethane Hydrate as a Phase Change

Material, J. Chem. Eng. Japan, 36, 788-793,

Indartono, Y. S, H. Usui, H. Suzuki and Y.

Komoda, Drag Reduction in a Turbulent Pipe

Flow of Trimethylolethane Hydrate Suspensions -

Effect of Pipe Diameter and Surfactant Additive

on Pressure Drop, Advance in Rheology and Its

Applications, Y. Luo, Q. Rao and Y. Xu, eds, pp

-572, Science Press USA, New Jersey, U.S.A,

a.

R. Darby, Hydrodynamics of Slurries and

Suspensions, Encyclopedia of Fluid Mechanics,

Vol. 5, Slurry Flow Technology, N. P.

Cheremisinoff, ed, pp. 49-91, Gulf Publishing

Company, Houston, U.S.A, 1986.

P. Pronk, T. M. Hansen, C. A. Infante Ferreira and

G. J. Witkamp, Time-Dependent Behavior of

Different Ice Slurries During Storage, Int. J.

Refrigeration, 28, 27-36, 2005.

H. Inaba, T. Inada, A. Horibe, H. Suzuki and H.

Usui, Preventing Agglomeration and Growth of

Ice Particles in Water With Suitable Additives, Int.

J. Refrigeration, 28, 20-26, 2005.

S. Grandum, A. Yabe, K. Nakagomi, M. Tanaka, F.

Takemura, Y. Kobayashi and P. E. Frivik, Analysis

of Ice Crystal Growth for a Crystal Surface

Containing Adsorbed Antifreeze Protein, J.

Crystal Growth, 205, 382-390, 1999.

T. Inada, A. Yabe, S. Grandum and T. Saito,

Control of Molecular-Level Ice Crystallization

Using Antifreeze Protein and Silane Coupling

Agent, Mat. Sci. Eng, A292, 149-154. 2000.

H. Usui, P. R. Modak, H. Suzuki and O. Okuma,

Suppression of Ice Particle Growth and the

Possibility of Energy Saving Latent Heat

Transportation by Using Surfactant Additives, J.

Chem. Eng. Japan, 37, 15-22, 2004a.

H. Suzuki, T. Itotagawa, Y. S. Indartono, H. Usui

and N. Wada, Rheological Characteristics

Trimethylolethane Hydrate Slurry Treated with

Drag-Reducing Surfactants, Rheol. Acta, accepted,

Y.S. Indartono, H. Usui, H. Suzuki, Y. Komoda

and K. Nakayama, Hydrodynamics and Heat

Transfer Characteristics of Drag-reducing

Trimethylolethane solution and suspension by

Cationic Surfactant, J. Chem. Eng. Japan, 39, 623

- 632, 2006a.

Y.S. Indartono, H. Usui, H. Suzuki, Y. Komoda

and K. Nakayama, Hydrodynamics and Heat

Transfer Characteristics of Trimethylolethane

Treated by Drag-reducing Cationic Surfactant at

Various Counter-Ion Concentration, Proceedings

of Fluid and Thermal Energy Conference (FTEC)

Jakarta December 2006, 2006b.

J.S. Lioumbas, A. A. Mouza and S. V. Paras,

Effect of Surfactant Additives on Co-Current

Gas-Liquid Downflow, Chem. Eng. Sci, 61, 4605

- 4616, 2006.

D. Rosso, D. L. Huo and M. K. Stenstrom,

Effect of Interfacial Surfactant Contamination

on Bubble Gas Transfer, Chem. Eng. Sci, 61,

- 5514, 2006.

W.A. Al-Masry and A. R. Dukkan, The Role of

Gas Disengagement and Surface Active Agents

on Hydrodynamic and Mass Transfer

Characteristics of Airlift Reactors, Chem. Eng. J,

, 263 - 271, 1997.

Z. Lin, B. Lu, J. L. Zakin, Y. Talmon, Y. Zheng,

H. T. Davis and L. E. Scriven, Influence of

Surfactant Concentration and Counterion to

Surfactant Ratio on Rheology of Wormlike

Micelles, J. Colloid and Interface Sci, 239,

-554, 2001.

B. Lu, Y. Zheng, H. T. Davis, L. E. Scriven, Y.

Talmon and J. L. Zakin, Effect of Variation in

Counterion to Surfactant Ratio on Rheology and

Microstructures of Drag Reducing Cationic

Surfactant Systems, Rheol. Acta, 37, 528-548,

Y. Hu and E. F. Matthys, The Effects of Salts on

the Rheological Characteristics of a

Drag-Reducing Cationic Surfactant Solution

With Shear-Induced Micellar Structures, Rheol.

Acta, 35, 470-480, 1996.

Y.S. Indartono, H. Usui, H. Suzuki and Y.

Komoda, Temperature and Diameter Effect on

Hydrodynamic Characteristic of Surfactant

Drag-Reducing Flows, Korea - Aust Rheol

Journal, 17, 157-164, 2005b.

H. Usui, T. Kamada and H. Suzuki, Surfactant

Drag Reduction Caused by A Cationic

Surfactant with Excess Addition of Counter-ions,

J. Chem. Eng. Japan, 37, 1232 - 1237, 2004b.

Diterbitkan

2017-05-15

Cara Mengutip

Indartono, Y. S., Usui, H., Suzuki, H., Tanaka, S., Nakayama, K., Komoda, Y., & Itotagawa, T. (2017). Particle Size Distribution and Rheolog ical Characteristic of Trimethylolethane Treated by Cationic Surfactant. Mesin, 22(2), 73-80. Diambil dari https://journals.itb.ac.id/index.php/jtms/article/view/4984

Terbitan

Bagian

Articles

Artikel paling banyak dibaca berdasarkan penulis yang sama